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This article is intended for Citrix administrators and technical teams only.
Non-admin users must contact their company’s Help Desk/IT support team and can refer to CTX297149 for more information.
Steps we need to follow to configure Receiver/Workspace app from GPO.

Copy Receiver.admx and Receiver.adml from C:Program Files (x86)CitrixICA ClientConfiguration and C:Program Files (x86)CitrixICA ClientConfigurationes-ES respectively
Note: Receiver.adml can be in a different directory for different language e.g. C:Program Files (x86)CitrixICA ClientConfigurationja-JP (for Japanese)
Paste Receiver.admx in %systemroot%policyDefinitions and Receiver.adml in %systemroot%policyDefinitionsen-us(for English) on Domain Controller

Open gpedit.msc or group policy management console on DC
Go to Computer Configuration>Administrative Templates>Citrix Component>Citrix Receiver>StoreFront
Enable 'NetScaler Gateway URL/StoreFront Accounts List' setting
Configuring for StoreFront URL:
Format to configure: Store Name;Store URL;Store enable state;Store Description
Store Name: Name of the store visible to users
Store URL: URL of the Store
Store enable state: If store is enable or disbale (On/Off)
Store Description: Description of Store visible to users
Example: OfficeStore;https://sf1.myurl.com/Citrix/Store/discovery;On;Store for office apps
Configuring for NetScaler URL:
Format to configure: Store Name;Store URL#Storename;Store enable state;Store Description
Example: OfficeStore;https://sf1.myurl.com#Storename;On;Store for office apps

Go to Computer Configuration>Administrative Templates>Citrix Component>Citrix Receiver>User authentication
Enable Local username and password policy
make sure to check 'Enable pass-though authentication' and 'Allow pass-through authentication for all ICA connection' in options for the policy

Save the settings and you will be able to see that all the devices getting the policy are configured with the Store in the policy and domain pass-through will work

https://docs.citrix.com/en-us/receiver/windows/4-9/secure-connections/config-pass-through.html